Reactive Intermediates In The Gas Phase

Author : D. W. Setser
Publisher : Elsevier
ISBN 13 : 1483220214
Total Pages : 369 pages
Book Rating : 4.15/5 ( download)

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Download or read book Reactive Intermediates in the Gas Phase written by D. W. Setser and published by Elsevier. This book was released on 2013-10-22 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Intermediates in the Gas Phase: Generation and Monitoring covers methods for reactive intermediates in the gas phase. The book discusses the generation and measurement of atom and radical concentrations in flow systems; the high temperature flow tubes, generation and measurement of refractory species; and the electronically excited long-lived states of atoms and diatomic molecules in flow systems. The text also describes the production and detection of reactive species with lasers in static systems; the production of small positive ions in a mass spectrometer; and the discharge-excited rare gas halide lasers. Chemists, physicists, and people working in aerochem laboratories will find the book invaluable.

Author : Robert A. Moss
Publisher : John Wiley & Sons
ISBN 13 : 9780471233244
Total Pages : 1088 pages
Book Rating : 4.42/5 ( download)

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Download or read book Reactive Intermediate Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2004-01-07 with total page 1088 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.

Author : Curt Wentrup
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.99/5 ( download)

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Download or read book Reactive Molecules written by Curt Wentrup and published by Wiley-Interscience. This book was released on 1984-03-21 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed for advanced undergraduate and graduate organic chemistry students, here's an up-to-date, in-depth textbook on the chemistry of neutral reactive intermediates--free radicals, diradicals, carbenes, nitrenes, strained rings, and antiaromatics. Includes numerous tables of physical data and extensive references to present day research in the field.

Author : Yannick Vallee
Publisher : CRC Press
ISBN 13 : 9789056990817
Total Pages : 322 pages
Book Rating : 4.10/5 ( download)

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Download or read book Gas Phase Reactions in Organic Synthesis written by Yannick Vallee and published by CRC Press. This book was released on 1998-01-29 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Flash Vacuum Thermolysis (FVT) techniques have become well-established methods and occupy an increasingly important place in synthesis. Gas Phase Reactions in Organic Synthesis is a complete review of the applications of flash vacuum thermolysis in organic chemistry; it features new developments in FVT, flow thermolysis and vacuum gas-solid reactions which have appeared in scientific literature since 1980.

Author : Leonardo S. Santos
Publisher : John Wiley & Sons
ISBN 13 : 9783527628735
Total Pages : 341 pages
Book Rating : 4.38/5 ( download)

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Download or read book Reactive Intermediates written by Leonardo S. Santos and published by John Wiley & Sons. This book was released on 2009-11-04 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades there has been considerable growth in the development of electrospray ionization mass spectrometry (ESI-MS) as a practical method in the study of reaction mechanisms. This method allows the interception and characterization of key intermediates, either as transient species or as protonated/deprotonated forms of neutral species by API-MS. The outstanding features and advantages of ESI-MS make it one of the most suitable tools for the fast screening of intermediates directly from solution, providing hitherto unavailable chemical information to organic chemists. This monograph provides an overview of the mechanisms involved in ESI-MS, the historical perspectives before looking further in-depth at specific reactions and intermediates. Written by researchers in the field, this book is an unique resource for the understanding of this cutting-edge technique.

Author : Thomas H. Osterheld
Publisher :
ISBN 13 :
Total Pages : 368 pages
Book Rating : 4.84/5 ( download)

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Download or read book Photochemical Studies of Reactive Intermediates Involved in Gas Phase Ion-neutral Reactions written by Thomas H. Osterheld and published by . This book was released on 1992 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : Samuel McManus
Publisher : Elsevier
ISBN 13 : 0323146279
Total Pages : 552 pages
Book Rating : 4.72/5 ( download)

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Download or read book Organic reactive intermediates written by Samuel McManus and published by Elsevier. This book was released on 2012-12-02 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation and investigation, factors affecting the stability, and reactions of the intermediate. Other topics include the formation and reaction of free radicals; kinetic aspects of free-radical chain reactions; electronic states and structures of carbenes; and formation of transient carbenes and carbenoids in solution. The intermediacy of nitrenes in reactions; electronic structure and spectra; methods of investigating carbonium ions; and reactions of carbonium ions are also elaborated. This publication likewise covers the preparation of carbanions; factors affecting the stability of carbanions; reactions involving radical ions; and methods of investigating arynes. This volume serves as a textbook for the first graduate-level course, as well as a reference for industrial chemists interested in organic reaction mechanisms.

Author : Harold S. Johnston
Publisher :
ISBN 13 :
Total Pages : 390 pages
Book Rating : 4.74/5 ( download)

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Download or read book Gas Phase Reaction Rate Theory written by Harold S. Johnston and published by . This book was released on 1966 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : Robert R. Snyder
Publisher : Springer Science & Business Media
ISBN 13 : 1475794800
Total Pages : 449 pages
Book Rating : 4.09/5 ( download)

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Download or read book Biological Reactive Intermediates V written by Robert R. Snyder and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: Much of organic chemistry is based on the ability of suitably structured chemicals to bind together through the formation of covalent bonds. Biochemistry is replete with exam ples of enzymatically catalyzed reactions in which normal body constituents can be linked through covalent bonds during the process of intermediary metabolism. The finding that xenobiotic chemicals that enter the body from the environment, are metabolized to highly reactive species, and then covalently react with cellular macromolecules to induce toxic and carcinogenic effects was an observation that spawned the research featured in the Fifth International Symposium on Biological Reactive Intermediates (BRI V). The group of investigators that became fascinated with this process and its signifi cance in terms of human health began their discussions in Turku, Finland (J 975), and continued them at Guildford, England (1980), College Park, Maryland (1985), Tucson, Arizona (1990), and Munich, Germany (1995). Among the results were a series of reports listed below, as well as the book for which this serves as the Preface. • Jollow, DJ., Kocsis, J.J., Snyder, R. and Vainio, H. (eds), Biological Reactive Intermediates: Formation, Toxicity and Inactivation, Plenum Press, NY, 1975. • Snyder, R., Park, D.V., Kocsis, J.J., Jollow, D.V., Gibson, G.G. and Witmer, C.M. (eds), Biological Reactive Intermediates II: Chemical Mechanisms and Biological Effects, Plenum Press, N.Y., 1982.

Author : Matthew S. Platz
Publisher : John Wiley & Sons
ISBN 13 : 0470120819
Total Pages : 492 pages
Book Rating : 4.11/5 ( download)

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Download or read book Reviews of Reactive Intermediate Chemistry written by Matthew S. Platz and published by John Wiley & Sons. This book was released on 2007-04-20 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter