The Chemistry Of Rotational Isomers

Author : Michinori Oki
Publisher : Springer Science & Business Media
ISBN 13 : 3642510248
Total Pages : 261 pages
Book Rating : 4.43/5 ( download)

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Download or read book The Chemistry of Rotational Isomers written by Michinori Oki and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rotation about the Carbon-Carbon single bond is generally regarded to be unrestricted. About 50 years ago, rotational isomers were found to exhibit optical activity: substituted biphenyl derivatives. However, the author has investigated other classes of compounds that have stable rotational isomers at room temperature. These compounds can serve as models for studying very weak intermolecular interactions, that are difficult to observe. Even diastereotopic groups show different chemical reactivity. From the contents: The "Free Rotation Concept" - Rotamer Populations - Barriers to Rotation - Reactivity of Rotational Isomers.

Author : Torsten Schmiermund
Publisher : Springer Nature
ISBN 13 : 3658320354
Total Pages : 56 pages
Book Rating : 4.55/5 ( download)

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Download or read book Introduction to Stereochemistry written by Torsten Schmiermund and published by Springer Nature. This book was released on 2021-06-07 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conformal, diastereomers, rotamers, tautomers, anomers: The multitude of terms used in stereochemistry quickly makes this subfield of chemistry confusing. In addition, there are different nomenclatures and different forms of representation (Fischer projection, Haworth ring formula, Newman projection). This essential deals with basic static stereochemistry and gives an overview of the different isomeric forms and nomenclatures. It is thus both a help and a reference book. This Springer essential is a translation of the original German 1st edition essentials, Einführung in die Stereochemie by Torsten Schmiermund, published by Springer Fachmedien Wiesbaden GmbH, part of Springer Nature in 2019. The translation was done with the help of artificial intelligence (machine translation by the service DeepL.com). A subsequent human revision was done primarily in terms of content, so that the book will read stylistically differently from a conventional translation. Springer Nature works continuously to further the development of tools for the production of books and on the related technologies to support the authors.

Author : San-Ichiro Mizushima
Publisher : Academic Press
ISBN 13 : 1483194833
Total Pages : 255 pages
Book Rating : 4.37/5 ( download)

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Download or read book Structure of Molecules and Internal Rotation written by San-Ichiro Mizushima and published by Academic Press. This book was released on 2013-10-22 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure of Molecules and Internal Rotation reviews early studies on dihalogenoethanes. This book is organized into two parts encompassing 8 chapters that evaluate the Raman effect in ethane derivatives, the energy difference between rotational isomers, and the infrared absorption of ethane derivatives. Some of the topics covered in the book are the potential barrier to internal rotation; nature of the hindering potential; entropy difference between the rotational isomers; internal rotation in butane, pentane, and hexane; and internal rotation in long chain n-paraffins. Other chapters deal with the configuration of a polypeptide chain, as well as the sum rule and the product rule for rotational isomers. The normal vibrations of the 1,2-dihalogenoethanes are presented. The last chapters are devoted to the examination of the Raman effect, dielectric constant, and electron diffraction. The book can provide useful information to chemists, physicists, students, and researchers.

Author : James E. Wollrab
Publisher : Academic Press
ISBN 13 : 148319485X
Total Pages : 485 pages
Book Rating : 4.51/5 ( download)

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Download or read book Rotational Spectra and Molecular Structure written by James E. Wollrab and published by Academic Press. This book was released on 2013-10-22 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Chemistry, A Series of Monographs: Rotational Spectra and Molecular Structure covers the energy levels and rotational transitions. This book is divided into nine chapters that evaluate the rigid asymmetric top molecules and the nuclear spin statistics for asymmetric tops. Some of the topics covered in the book are the asymmetric rotor functions; rotational transition intensities; classes of molecules; nuclear spin statistics for linear molecules and symmetric tops; and classical appearance of centrifugal and coriolis forces. Other chapters deal with the energy levels and effects of centrifugal distortion, as well as the internuclear distance and moments of inertia. The discussion then shifts to the coriolis coupling effects on rotational constants and the perturbation treatment of vibration-rotational Hamiltonian. The last chapter is devoted to the examination of origin of the quadrupole interaction. The book can provide useful information to chemists, physicists, electrical engineers, students, and researchers.

Author : San-Ichiro Mizushima
Publisher :
ISBN 13 : 9781483167350
Total Pages : pages
Book Rating : 4.56/5 ( download)

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Download or read book Structure of Molecules and Internal Rotation written by San-Ichiro Mizushima and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure of Molecules and Internal Rotation reviews early studies on dihalogenoethanes. This book is organized into two parts encompassing 8 chapters that evaluate the Raman effect in ethane derivatives, the energy difference between rotational isomers, and the infrared absorption of ethane derivatives. Some of the topics covered in the book are the potential barrier to internal rotation; nature of the hindering potential; entropy difference between the rotational isomers; internal rotation in butane, pentane, and hexane; and internal rotation in long chain n-paraffins. Other chapters deal wi ...

Author :
Publisher :
ISBN 13 : 9780121730505
Total Pages : 524 pages
Book Rating : 4.06/5 ( download)

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Download or read book Conformational Analysis written by and published by . This book was released on 1971 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : John D. Roberts
Publisher :
ISBN 13 : 9780805383218
Total Pages : 1596 pages
Book Rating : 4.12/5 ( download)

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Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Author : Mavis Redshaw
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 634 pages
Book Rating : 4.89/5 ( download)

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Download or read book Internal Rotation in Molecules written by Mavis Redshaw and published by John Wiley & Sons. This book was released on 1974 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : Hans Landolt
Publisher :
ISBN 13 :
Total Pages : 180 pages
Book Rating : 4.52/5 ( download)

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Download or read book Optical Activity and Chemical Composition written by Hans Landolt and published by . This book was released on 1899 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : John M. Brown
Publisher : Cambridge University Press
ISBN 13 : 9780521530781
Total Pages : 1074 pages
Book Rating : 4.84/5 ( download)

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Download or read book Rotational Spectroscopy of Diatomic Molecules written by John M. Brown and published by Cambridge University Press. This book was released on 2003-04-10 with total page 1074 pages. Available in PDF, EPUB and Kindle. Book excerpt: The definitive text on the rotational spectroscopy of diatomic molecules.