Solitons And Polarons In Conducting Polymers

Author : Lu Yu
Publisher : World Scientific
ISBN 13 : 981459685X
Total Pages : 772 pages
Book Rating : 4.55/5 ( download)

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Download or read book Solitons And Polarons In Conducting Polymers written by Lu Yu and published by World Scientific. This book was released on 1988-08-01 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.

Author : Lu Yu
Publisher : World Scientific
ISBN 13 : 9789971500542
Total Pages : 774 pages
Book Rating : 4.4X/5 ( download)

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Download or read book Solitons & Polarons in Conducting Polymers written by Lu Yu and published by World Scientific. This book was released on 1988 with total page 774 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.

Author : Lu Yu
Publisher : World Scientific Publishing Company Incorporated
ISBN 13 : 9789971500535
Total Pages : 754 pages
Book Rating : 4.31/5 ( download)

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Download or read book Solitons & Polarons in Conducting Polymers written by Lu Yu and published by World Scientific Publishing Company Incorporated. This book was released on 1988 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.

Author : Meixiang Wan
Publisher : Springer Science & Business Media
ISBN 13 : 3540693238
Total Pages : 307 pages
Book Rating : 4.39/5 ( download)

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Download or read book Conducting Polymers with Micro or Nanometer Structure written by Meixiang Wan and published by Springer Science & Business Media. This book was released on 2009-03-15 with total page 307 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conducting Polymers with Micro or Nanometer Structure describes a topic discovered by three winners of the Nobel Prize in Chemistry in 2000: Alan J. Heeger, University of California at Santa Barbara, Alan G. MacDiarmid at the University of Pennsylvania, and Hideki Shirakawa at the University of Tsukuba. Since then, the unique properties of conducting polymers have led to promising applications in functional materials and technologies. The book first briefly summarizes the main concepts of conducting polymers before introducing micro/nanostructured conducting polymers dealing with their synthesis, structural characterizations, formation mechanisms, physical and chemical properties, and potential applications in nanomaterials and nanotechnology. The book is intended for researchers in the related fields of chemistry, physics, materials, nanomaterials and nanodevices. Meixiang Wan is a professor at the Institute of Chemistry, Chinese Academy of Sciences, Beijing.

Author : Helmut Kiess
Publisher : Springer Science & Business Media
ISBN 13 : 3642467296
Total Pages : 320 pages
Book Rating : 4.95/5 ( download)

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Download or read book Conjugated Conducting Polymers written by Helmut Kiess and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews the current understanding of electronic, optical and magnetic properties of conjugated polymers in both the semiconducting and metallic states. It introduces in particular novel phenomena and concepts in these quasi one-dimensional materials that differ from the well-established concepts valid for crystalline semiconductors. After a brief introductory chapter, the second chapter presents basic theore tical concepts and treats in detail the various models for n-conjugated polymers and the computational methods required to derive observable quantities. Specific spatially localized structures, often referred to as solitons, polarons and bipolarons, result naturally from the interaction between n-electrons and lattice displacements. For a semi-quantitative understanding of the various measure ments, electron-electron interactions have to be incorporated in the models; this in turn makes the calculations rather complicated. The third chapter is devoted to the electrical properties of these materials. The high metallic conductivity achieved by doping gave rise to the expression conducting polymers, which is often used for such materials even when they are in their semiconducting or insulating state. Although conductivity is one of the most important features, the reader will learn how difficult it is to draw definite conclusions about the nature of the charge carriers and the microscopic transport mechanism solely from electrical measurements. Optical properties are discussed in the fourth chapter.

Author : Alan J. Heeger
Publisher : OUP Oxford
ISBN 13 : 0198528647
Total Pages : 288 pages
Book Rating : 4.47/5 ( download)

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Download or read book Semiconducting and Metallic Polymers written by Alan J. Heeger and published by OUP Oxford. This book was released on 2010-07-29 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: The unique properties of conducting and semiconducting (conjugated) polymers make them one of the most attractive areas of interdisciplinary materials science and technology. Written by a pioneer in the field, this book is the first aimed at teaching graduate students, postdoctoral scientists, and specialists in industry about this exciting field.

Author : Prasanna Chandrasekhar
Publisher : Springer Science & Business Media
ISBN 13 : 1461552451
Total Pages : 740 pages
Book Rating : 4.51/5 ( download)

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Download or read book Conducting Polymers, Fundamentals and Applications written by Prasanna Chandrasekhar and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the practical fundamentals and applications of conducting polymers. Written from a pedagogical point of view and at a very basic level, it provides a thorough grounding in CPs ideal for further work, as a reference, or as a supplementary course text.

Author : Shangzhi Chen
Publisher : Linköping University Electronic Press
ISBN 13 : 9179297455
Total Pages : 142 pages
Book Rating : 4.59/5 ( download)

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Download or read book Optics of Conducting Polymer Thin Films and Nanostructures written by Shangzhi Chen and published by Linköping University Electronic Press. This book was released on 2021-02-19 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intrinsically conducting polymers forms a category of doped conjugated polymers that can conduct electricity. Since their discovery in the late 1970s, they have been widely applied in many fields, ranging from optoelectronic devices to biosensors. The most common type of conducting polymers is poly(3,4-ethylenedioxythiophene), or PEDOT. PEDOT has been popularly used as electrodes for solar cells or light-emitting diodes, as channels for organic electrochemical transistors, and as p-type legs for organic thermoelectric generators. Although many studies have been dedicated to PEDOT-based materials, there has been a lack of a unified model to describe their optical properties across different spectral ranges. In addition, the interesting optical properties of PEDOT-based materials, benefiting from its semi-metallic character, have only been rarely studied and utilized, and could potentially enable new applications. Plasmonics is a research field focusing on interactions between light and metals, such as the noble metals (gold and silver). It has enabled various opportunities in fundamental photonics as well as practical applications, varying from biosensors to colour displays. This thesis explores highly conducting polymers as alternatives to noble metals and as a new type of active plasmonic materials. Despite high degrees of microstructural disorder, conducting polymers can possess electrical conductivity approaching that of poor metals, with particularly high conductivity for PEDOT deposited via vapour phase polymerization (VPP). In this thesis, we systematically studied the optical and structural properties of VPP PEDOT thin films and their nanostructures for plasmonics and other optical applications. We employed ultra-wide spectral range ellipsometry to characterize thin VPP PEDOT films and proposed an anisotropic Drude-Lorentz model to describe their optical conductivity, covering the ultraviolet, visible, infrared, and terahertz ranges. Based on this model, PEDOT doped with tosylate (PEDOT:Tos) presented negative real permittivity in the near infrared range. While this indicated optical metallic character, the material also showed comparably large imaginary permittivity and associated losses. To better understand the VPP process, we carefully examined films with a collection of microstructural and spectroscopic characterization methods and found a vertical layer stratification in these polymer films. We unveiled the cause as related to unbalanced transport of polymerization precursors. By selection of suitable counterions, e.g., trifluoromethane sulfonate (OTf), and optimization of reaction conditions, we were able to obtain PEDOT films with electrical conductivity exceeding 5000 S/cm. In the near infrared range from 1 to 5 µm, these PEDOT:OTf films provided a well-defined plasmonic regime, characterized by negative real permittivity and lower magnitude imaginary component. Using a colloidal lithography-based approach, we managed to fabricate nanodisks of PEDOT:OTf and showed that they exhibited clear plasmonic absorption features. The experimental results matched theoretical calculations and numerical simulations. Benefiting from their mixed ionic-electronic conducting characters, such organic plasmonic materials possess redox-tunable properties that make them promising as tuneable optical nanoantennas for spatiotemporally dynamic systems. Finally, we presented a low-cost and efficient method to create structural colour surfaces and images based on UV-treated PEDOT films on metallic mirrors. The concept generates beautiful and vivid colours through-out the visible range utilizing a synergistic effect of simultaneously modulating polymer absorption and film thickness. The simplicity of the device structure, facile fabrication process, and tunability make this proof-of-concept device a potential candidate for future low-cost backlight-free displays and labels.

Author : Victor I. Krinichnyi
Publisher : CRC Press
ISBN 13 : 1498779654
Total Pages : 315 pages
Book Rating : 4.54/5 ( download)

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Download or read book Multi Frequency EPR Spectroscopy of Conjugated Polymers and Their Nanocomposites written by Victor I. Krinichnyi and published by CRC Press. This book was released on 2016-10-14 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conjugated polymeric materials and their nanocomposites are widely used for the creation of alternative sources of renewable energy, cell phone screens, mobile gadgets, video players and OLED-TV, as well as organic diodes, transistors, sensors, etc. with field-dependent and spin-assisted electronic properties. Multifrequency EPR Spectroscopy methods can help researchers optimize their structural, magnetic and electronic properties for the creation of more efficient molecular devices. This book will acquaint the reader with the basic properties of conjugated polymers, the fundamentals of EPR Spectroscopy, and the information that can be obtained at different wavebands of EPR spectroscopy.

Author : Dr. Manjula S. & Dr. Sangshetty Kalyane
Publisher : Horizon Books ( A Division of Ignited Minds Edutech P Ltd)
ISBN 13 : 9386369486
Total Pages : 104 pages
Book Rating : 4.82/5 ( download)

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Download or read book MICROWAVE PROPERTIES OF CONDUCTING POLYMER COMPOSITES written by Dr. Manjula S. & Dr. Sangshetty Kalyane and published by Horizon Books ( A Division of Ignited Minds Edutech P Ltd). This book was released on 2021-05-05 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: