Scorpionates Ii

Author : Claudio Pettinari
Publisher : Imperial College Press
ISBN 13 : 1860948774
Total Pages : 570 pages
Book Rating : 4.70/5 ( download)

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Download or read book Scorpionates II written by Claudio Pettinari and published by Imperial College Press. This book was released on 2008 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since their discovery by Swiatoslaw Trofimenko in 1967, poly(pyrazol-1-yl)borates have been considered as one of the most useful ligands in modern coordination chemistry. The term OC scorpionateOCO has been used to describe the interchange between bidentate and tridentate coordination modes by these ligands that has been employed for the synthesis of complexes with virtually every metal in the periodic table, having applications in diverse fields ranging from homogeneous catalysis to bioinorganic chemistry.This all-inclusive reference book continues where Trofimenko''s original work left off. It not only includes discussions on all new ligands reported from 1999 to date, but also introduces new ligands that have yet to be touched upon in other titles, such as scorpionates based on S donors or P donors. As such, this comprehensive volume is a OC must haveOCO for all researchers who utilize this family of molecules."

Author : Claudio Pettinari
Publisher : World Scientific
ISBN 13 : 1908979070
Total Pages : 572 pages
Book Rating : 4.70/5 ( download)

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Download or read book Scorpionates II: Chelating Borate Ligands written by Claudio Pettinari and published by World Scientific. This book was released on 2008-05-29 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since their discovery by Swiatoslaw Trofimenko in 1967, poly(pyrazol-1-yl)borates have been considered as one of the most useful ligands in modern coordination chemistry. The term “scorpionate” has been used to describe the interchange between bidentate and tridentate coordination modes by these ligands that has been employed for the synthesis of complexes with virtually every metal in the periodic table, having applications in diverse fields ranging from homogeneous catalysis to bioinorganic chemistry. This all-inclusive reference book continues where Trofimenko's original work left off. It not only includes discussions on all new ligands reported from 1999 to date, but also introduces new ligands that have yet to be touched upon in other titles, such as scorpionates based on S donors or P donors. As such, this comprehensive volume is a “must have” for all researchers who utilize this family of molecules. Contents: Homoscorpionates — First GenerationHomoscorpionates — Second GenerationHeteroscorpionatesScorpionates Based on Thioimidazolones as Sulfur Donors and Related LigandsScorpionates Based on Thioethers as Sulfur DonorsScorpionates Based on Diaryl or Dialkylphosphine as DonorsApplicationConcluding Remarks Readership: Chemists from academic institutions and industries interested in coordination chemistry, catalysis, and advanced materials; biologists interested in bioinorganic studies. Keywords:Scorpionates;Poly(pyrazolyl)borates;Trofimenko;Metal Complexes;Homoscorpionates;Heteroscorpionates;Chelating Borate Donors;Tripodal Donors;C-H Activation;Enzyme Modeling;Coordination Polymers;PolymerizationKey Features:Contains the most complete collection of references on scorpionatesAuthor has published more than 250 papers in international journals, and was awarded the highly regarded 2004 Raffaello Nasini Medal from the Inorganic Chemistry Division of the Italian Society of Chemistry

Author : Swiatoslaw Trofimenko
Publisher : World Scientific
ISBN 13 : 1783261994
Total Pages : 292 pages
Book Rating : 4.94/5 ( download)

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Download or read book Scorpionates written by Swiatoslaw Trofimenko and published by World Scientific. This book was released on 1999-08-16 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book. The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances. Contents: IntroductionHomoscorpionates — First GenerationHomoscorpionates — Second GenerationHeteroscorpionates, RR'BpxApplications of Scorpionate Ligands Readership: Inorganic chemists. Keywords:Scorpionaters;Polypyrazolylborates;Homoscorpionates;Heteroscorpionates;Coordination Chemistry;Catalysis;Extraction;Bioinorganic Modeling;Ligands;PyrazabolesReviews:“This important book, laden with chemical facts, is useful and well written … Exhaustive coverage of scorpionate ligands establishes this book as the definitive source for anyone considering any aspect of scorpionate chemistry.”J. Am. Chem. Soc. “This book is essential for every researcher who makes use of Tp ligands and wishes to avoid duplicating work that has already been reported.”Angew. Chem. Int. Ed.

Author : Claudio Pettinari
Publisher : World Scientific
ISBN 13 : 1860948766
Total Pages : 570 pages
Book Rating : 4.63/5 ( download)

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Download or read book Scorpionates II written by Claudio Pettinari and published by World Scientific. This book was released on 2008 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: This resource continues where Trofimenko's original work left off. It not only includes discussions on all new ligands reported from 1999 to date, but also introduces new ligands, such as scorpionates based on S donors or P donors. As such, this volume is a 'must-have' for all researchers who use this family of molecules.

Author :
Publisher : Academic Press
ISBN 13 : 0128050764
Total Pages : 396 pages
Book Rating : 4.67/5 ( download)

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Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 2016-05-25 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry contains authoritative review articles of world-wide known researchers on the field of organometallic chemistry, covering topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. The book will benefit a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies, and practical applications. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on all the latest developments in the field Carefully edited to provide easy-to-read material

Author : Gareth Owen
Publisher : MDPI
ISBN 13 : 3039215841
Total Pages : 110 pages
Book Rating : 4.43/5 ( download)

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Download or read book Metal Complexes Containing Boron Based Ligands written by Gareth Owen and published by MDPI. This book was released on 2019-10-30 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Author : Chao-Jun Li
Publisher : John Wiley & Sons
ISBN 13 : 3527342818
Total Pages : 848 pages
Book Rating : 4.15/5 ( download)

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Download or read book Silver Catalysis in Organic Synthesis, 2 Volume Set written by Chao-Jun Li and published by John Wiley & Sons. This book was released on 2019-04-29 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers all the aspects of the recent achievements in silver catalyzed reactions Silver catalysis has emerged as a powerful tool in the field of organic synthesis. This comprehensive book systematically explores the unique performance of silver catalysis, introducing all the recent progress of silver catalysis in organic synthesis. It clearly emphasizes the unique features of silver catalysis and provides the reaction mechanism involved. This two-volume book also provides vivid schematics and tables throughout to enhance the accessibility to the relevant theory and mechanisms. Silver Catalysis in Organic Synthesis begins with an introduction to Silver Chemistry before moving on to chapters covering: Silver-Catalyzed Cycloaddition Reactions; Silver-Catalyzed Cyclizations; Silver-Mediated Radical Reactions; Silver-Mediated Fluorination, Perfluoroalkylation and Trifluoromethylthiolation Reactions; Coupling Reactions and C-H Functionalization; Silver-Catalyzed CO2 Incorporation; Silver-Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions; Asymmetric Silver-Catalyzed Reactions; Silver-Catalyzed Reduction and Oxidation of Aldehydes and Their Derivatives; Silver Complexes in Organic Transformations; and Silver Nanoparticles in Organic Transformations. -Covers recently developed organic reactions catalyzed by silver, along with their reaction mechanism -Introduces many new reactions and mechanisms related to silver catalysis -Offers professionals and newcomers in the related fields a survey of new advances in silver catalysis in organic synthesis Silver Catalysis in Organic Synthesis will appeal to a wide readership including chemists, biochemists, pharmaceutical scientists, biomedical researchers, agriculture scientists, and graduate students in the related fields.

Author : Armando J L Pombeiro
Publisher : World Scientific
ISBN 13 : 9811279950
Total Pages : 2103 pages
Book Rating : 4.59/5 ( download)

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Download or read book Synthesis And Applications In Chemistry And Materials (In 4 Volumes) written by Armando J L Pombeiro and published by World Scientific. This book was released on 2024-01-16 with total page 2103 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and Material Sciences naturally depend greatly on Synthesis as the initial stage for the existence of compounds and materials with desired behaviors, within the overall streamline of Design/Synthesis — Properties — Application/Function, and their relations. Such a general approach is of a too wide scope to be properly treated in a single set of publications, but this one on 'Synthesis and Applications in Chemistry and Materials' restricts itself by aiming to show the strength and international character of the current research in synthetic chemistry that is being developed in Portugal or abroad by teams that cooperate with this country. Hence, it gathers representative contributions of main Portuguese research groups and foreign collaborating ones. Nevertheless, the topic should be understood in a wide sense, being open to types of studies with significance on sustainable synthesis and applications in chemistry, materials and/or related sciences.

Author : Manas Sutradhar
Publisher : Royal Society of Chemistry
ISBN 13 : 1839160896
Total Pages : 513 pages
Book Rating : 4.99/5 ( download)

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Download or read book Vanadium Catalysis written by Manas Sutradhar and published by Royal Society of Chemistry. This book was released on 2020-11-05 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.

Author : Roger Alberto
Publisher : Springer Science & Business Media
ISBN 13 : 9783540225775
Total Pages : 252 pages
Book Rating : 4.73/5 ( download)

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Download or read book Contrast Agents III written by Roger Alberto and published by Springer Science & Business Media. This book was released on 2005-02-10 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: with contributions by numerous experts