Organic Sulfur Compounds

Author : N. Kharasch
Publisher : Elsevier
ISBN 13 : 1483224856
Total Pages : 637 pages
Book Rating : 4.55/5 ( download)

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Download or read book Organic Sulfur Compounds written by N. Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.

Author : Norman Kharasch
Publisher : Elsevier
ISBN 13 : 1483156117
Total Pages : 475 pages
Book Rating : 4.18/5 ( download)

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Download or read book The Chemistry of Organic Sulfur Compounds written by Norman Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Organic Sulfur Compounds deals with the chemistry of organic sulfur compounds such as thiocyanates, 1-alkynyl thioethers, thiols, and olefins. Topics covered range from the mechanisms of Raney nickel desulfuration to olefin sulfide chemistry, desulfonylation reactions, and alkaline decomposition of aliphatic disulfides. The reaction of cyanide with cystine and cystine peptides is also discussed. This volume is comprised of 15 chapters and begins with an introduction to electron correlation and bond properties in some selected sulfur compounds including thionyl and sulfuryl fluoride. The following chapters explore the mechanisms of Raney nickel desulfuration; isomerization of organic thiocyanates; polyfluoroalkyl derivatives of sulfur; anionic oxidation of thiols and co-oxidation of thiols with olefins; and the chemistry of the 1,2-sithiole ring. Thiohydantoins, thiophosgene, and the alkaline decomposition of aliphatic disulfides are also considered. The final chapter is devoted to oxidation of disulfides, with special reference to cystine. This book will be a useful resource for organic chemists.

Author : Norman Karasch
Publisher :
ISBN 13 :
Total Pages : 664 pages
Book Rating : 4.00/5 ( download)

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Download or read book Organic Sulfur Compounds written by Norman Karasch and published by . This book was released on 1961 with total page 664 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : S. Oae
Publisher : Springer Science & Business Media
ISBN 13 : 1468420496
Total Pages : 714 pages
Book Rating : 4.94/5 ( download)

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Download or read book Organic Chemistry of Sulfur written by S. Oae and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.

Author : Norman Kharasch
Publisher :
ISBN 13 :
Total Pages : 624 pages
Book Rating : 4.01/5 ( download)

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Download or read book Organic Sulfur Compounds written by Norman Kharasch and published by . This book was released on 1961 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : Shigeru Oae
Publisher : CRC Press
ISBN 13 : 1351092170
Total Pages : 441 pages
Book Rating : 4.73/5 ( download)

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Download or read book Organic Sulfur Chemistry written by Shigeru Oae and published by CRC Press. This book was released on 2018-05-04 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains fundamental knowledge regarding the structure and mechanisms of organic sulfur chemistry. Topics include sulfur bondings, effects of sulfur groups, stereochemistry around sulfur, substitution, ligand coupling within s-sulfurane, oxidation, reduction and rearrangement. References in this work total over 2,300. Anyone with an interest in organic sulfur chemistry will find this book to be fascinating reading.

Author : Norman Kharasch
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.92/5 ( download)

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Download or read book Organic Sulfur Compounds written by Norman Kharasch and published by . This book was released on 1961 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.40/5 ( download)

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Download or read book The Chemistry of Organic Sulfur Compounds written by and published by . This book was released on 1961 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : Norman Kharasch
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.92/5 ( download)

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Download or read book Organic Sulfur Compounds written by Norman Kharasch and published by . This book was released on 1961 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : C. Christophersen
Publisher : CRC Press
ISBN 13 : 9783718603374
Total Pages : 94 pages
Book Rating : 4.73/5 ( download)

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Download or read book Organic Sulfur Compounds from Marine Organisms written by C. Christophersen and published by CRC Press. This book was released on 1986 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: