N Heterocyclic Carbenes In Synthesis

Author : Steven P. Nolan
Publisher : John Wiley & Sons
ISBN 13 : 9783527314003
Total Pages : 330 pages
Book Rating : 4.08/5 ( download)

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Download or read book N-Heterocyclic Carbenes in Synthesis written by Steven P. Nolan and published by John Wiley & Sons. This book was released on 2006-10-27 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.

Author : Silvia Diez-Gonzalez
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626816
Total Pages : 636 pages
Book Rating : 4.17/5 ( download)

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Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Author : Akkattu T. Biju
Publisher : John Wiley & Sons
ISBN 13 : 3527809058
Total Pages : 407 pages
Book Rating : 4.59/5 ( download)

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Download or read book N-Heterocyclic Carbenes in Organocatalysis written by Akkattu T. Biju and published by John Wiley & Sons. This book was released on 2019-01-07 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. Alongside comprehensive coverage of the synthesis, characteristics and applications, this handbook and ready reference also includes chapters on NHCs for polymerization reactions and natural product synthesis.

Author : Frank Glorius
Publisher : Springer
ISBN 13 : 3540369309
Total Pages : 240 pages
Book Rating : 4.01/5 ( download)

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Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis written by Frank Glorius and published by Springer. This book was released on 2007-02-05 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

Author : Steven P. Nolan
Publisher : Wiley-VCH
ISBN 13 : 9783527334902
Total Pages : 0 pages
Book Rating : 4.04/5 ( download)

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Download or read book N-Heterocyclic Carbenes written by Steven P. Nolan and published by Wiley-VCH. This book was released on 2014-11-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist.

Author : Silvia Díez-González
Publisher : Royal Society of Chemistry
ISBN 13 : 1849730423
Total Pages : 469 pages
Book Rating : 4.26/5 ( download)

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Download or read book N-heterocyclic Carbenes written by Silvia Díez-González and published by Royal Society of Chemistry. This book was released on 2011 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last fifteen years, N-heterocyclic carbenes (NHCs) have mostly been used as ancillary ligands for the preparation of transition metal-based catalysts. Compared to phosphorus-containing ligands, NHCs tend to bind more strongly to metal centres, avoiding the necessity for the use of excess ligand in catalytic reactions. The corresponding complexes are often less sensitive to air and moisture, and have proven remarkably resistant to oxidation. Recent developments in catalysis applications have been facilitated by the availability of carbenes stable enough to be bottled, particularly for their use as organocatalysts. This book shows how N-heterocyclic carbenes can be useful in various fields of chemistry and not merely laboratory curiosities or simple phosphine mimics. NHCs are best known for their contribution to ruthenium and palladium-catalysed reactions but the scope of this book is much broader. The synthesis of NHC ligands and their corresponding metal complexes are covered in depth. Moreover, the biological activity of NHC-containing complexes, as well as an overview of their theoretical aspects are included. Such metal species are further examined, not only in terms of their catalytic applications, but also of their stereoelectronic parameters and reactivity/stability. Finally, special attention is given to the hot topic of organocatalysis. The book will be of interest to postgraduates, academic researchers and those working in industry.

Author : Steven Nolan
Publisher : Thieme
ISBN 13 : 3132013315
Total Pages : 807 pages
Book Rating : 4.15/5 ( download)

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Download or read book Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 1 written by Steven Nolan and published by Thieme. This book was released on 2017-06-14 with total page 807 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Author : Steven P. Nolan
Publisher : John Wiley & Sons
ISBN 13 : 3527671242
Total Pages : 690 pages
Book Rating : 4.43/5 ( download)

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Download or read book N-Heterocyclic Carbenes written by Steven P. Nolan and published by John Wiley & Sons. This book was released on 2014-07-07 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist.

Author : Steven Nolan
Publisher : Thieme
ISBN 13 : 3132414034
Total Pages : 816 pages
Book Rating : 4.37/5 ( download)

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Download or read book Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 2 written by Steven Nolan and published by Thieme. This book was released on 2017-06-14 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. "Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis" presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Author : David Morales-Morales
Publisher : Elsevier
ISBN 13 : 0080545157
Total Pages : 467 pages
Book Rating : 4.58/5 ( download)

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Download or read book The Chemistry of Pincer Compounds written by David Morales-Morales and published by Elsevier. This book was released on 2011-08-11 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known