Lithium Metal Anodes And Rechargeable Lithium Metal Batteries

Author : Ji-Guang Zhang
Publisher : Springer
ISBN 13 : 3319440543
Total Pages : 194 pages
Book Rating : 4.45/5 ( download)

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Download or read book Lithium Metal Anodes and Rechargeable Lithium Metal Batteries written by Ji-Guang Zhang and published by Springer. This book was released on 2016-10-06 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Author : Ji-Guang Zhang
Publisher : Springer
ISBN 13 : 9783319440538
Total Pages : 0 pages
Book Rating : 4.35/5 ( download)

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Download or read book Lithium Metal Anodes and Rechargeable Lithium Metal Batteries written by Ji-Guang Zhang and published by Springer. This book was released on 2016-10-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Author : M. C. Smart
Publisher : The Electrochemical Society
ISBN 13 : 1566776422
Total Pages : 177 pages
Book Rating : 4.24/5 ( download)

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Download or read book Rechargeable Lithium and Lithium Ion Batteries written by M. C. Smart and published by The Electrochemical Society. This book was released on 2008-05 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Rechargeable Lithium and Lithium Ion Batteries¿, held during the 212th meeting of The Electrochemical Society, in Washington, DC, from October 7 to 12, 2007.

Author : Doron Aurbach
Publisher : CRC Press
ISBN 13 : 9780824741389
Total Pages : 980 pages
Book Rating : 4.82/5 ( download)

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Download or read book Nonaqueous Electrochemistry written by Doron Aurbach and published by CRC Press. This book was released on 1999-07-27 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt: An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.

Author : Rachid Yazami
Publisher : CRC Press
ISBN 13 : 9814364231
Total Pages : 452 pages
Book Rating : 4.32/5 ( download)

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Download or read book Nanomaterials for Lithium-Ion Batteries written by Rachid Yazami and published by CRC Press. This book was released on 2013-10-08 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most recent advances in the science and technology of nanostructured materials for lithium-ion application. With contributions from renowned scientists and technologists, the chapters discuss state-of-the-art research on nanostructured anode and cathode materials, some already used in commercial batteries and others still in de

Author : Kiyoshi Kanamura
Publisher : Springer Nature
ISBN 13 : 9813366680
Total Pages : 580 pages
Book Rating : 4.88/5 ( download)

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Download or read book Next Generation Batteries written by Kiyoshi Kanamura and published by Springer Nature. This book was released on 2021-03-23 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the development of next-generation batteries is introduced. Included are reports of investigations to realize high energy density batteries: Li-air, Li-sulfur, and all solid-state and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid electrolytes are also reviewed.A number of relevant aspects of all solid-state batteries with a carbon anode or Li-metal anode are discussed and described: The formation of the cathode; the interface between the cathode (anode) and electrolyte; the discharge and charge mechanisms of the Li-air battery; the electrolyte system for the Li-air battery; and cell construction. The Li-sulfur battery involves a critical problem, namely, the dissolution of intermediates of sulfur during the discharge process. Here, new electrolyte systems for the suppression of intermediate dissolution are discussed. Li-metal batteries with liquid electrolytes also present a significant problem: the dendrite formation of lithium. New separators and electrolytes are introduced to improve the safety and rechargeability of the Li-metal anode. Mg, Al, and Zn metal anodes have been also applied to rechargeable batteries, and in this book, new metal anode batteries are introduced as the generation-after-next batteries.This volume is a summary of ALCA-SPRING projects, which constitute the most extensive research for next-generation batteries in Japan. The work presented in this book is highly informative and useful not only for battery researchers but also for researchers in the fields of electric vehicles and energy storage.

Author : Yu Yan
Publisher : OAE Publishing Inc.
ISBN 13 :
Total Pages : 32 pages
Book Rating : 4./5 ( download)

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Download or read book Lithium metal stabilization for next-generation lithium-based batteries: from fundamental chemistry to advanced characterization and effective protection written by Yu Yan and published by OAE Publishing Inc.. This book was released on 2023-01-11 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium (Li) metal-based rechargeable batteries hold significant promise to meet the ever-increasing demands for portable electronic devices, electric vehicles and grid-scale energy storage, making them the optimal alternatives for next-generation secondary batteries. Nevertheless, Li metal anodes currently suffer from major drawbacks, including safety concerns, capacity decay and lifespan degradation, which arise from uncontrollable dendrite growth, notorious side reactions and infinite volume variation, thereby limiting their current practical application. Numerous critical endeavors from different perspectives have been dedicated to developing highly stable Li metal anodes. Herein, a comprehensive overview of Li metal anodes regarding fundamental mechanisms, scientific challenges, characterization techniques, theoretical investigations and advanced strategies is systematically presented. First, the basic working principles of Li metal-based batteries are introduced. Specific attention is then paid to the fundamental understanding of and challenges facing Li metal anodes. Accordingly, advanced characterization approaches and theoretical computations are introduced to understand the fundamental mechanisms of dendrite growth and parasitic reactions. Recent key progress in Li anode protection is then comprehensively summarized and categorized to generate an overview of the respective superiorities and limitations of the various strategies. Furthermore, this review concludes the remaining obstacles and potential research directions for inspiring the innovation of Li metal anodes and endeavors to accomplish the practical application of next-generation Li-based batteries.

Author : Gabin Yoon
Publisher : Springer Nature
ISBN 13 : 9811389144
Total Pages : 75 pages
Book Rating : 4.46/5 ( download)

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Download or read book Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries written by Gabin Yoon and published by Springer Nature. This book was released on 2022-07-08 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes in-depth theoretical efforts to understand the reaction mechanism of graphite and lithium metal as anodes for next-generation rechargeable batteries. The first part deals with Na intercalation chemistry in graphite, whose understanding is crucial for utilizing graphite as an anode for Na-ion batteries. The author demonstrates that Na ion intercalation in graphite is thermodynamically unstable because of the unfavorable Na-graphene interaction. To address this issue, the inclusion of screening moieties, such as solvents, is suggested and proven to enable reversible Na-solvent cointercalation in graphite. Furthermore, the author provides the correlation between the intercalation behavior and the properties of solvents, suggesting a general strategy to tailor the electrochemical intercalation chemistry. The second part addresses the Li dendrite growth issue, which is preventing practical application of Li metal anodes. A continuum mechanics study considering various experimental conditions reveals the origins of irregular growth of Li metal. The findings provide crucial clues for developing effective counter strategies to control the Li metal growth, which will advance the application of high-energy-density Li metal anodes.

Author : Bruno Scrosati
Publisher : John Wiley & Sons
ISBN 13 : 1118615395
Total Pages : 495 pages
Book Rating : 4.93/5 ( download)

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Download or read book Lithium Batteries written by Bruno Scrosati and published by John Wiley & Sons. This book was released on 2013-06-18 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.

Author : Thandavarayan Maiyalagan
Publisher : CRC Press
ISBN 13 : 1351052683
Total Pages : 339 pages
Book Rating : 4.89/5 ( download)

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Download or read book Rechargeable Lithium-Ion Batteries written by Thandavarayan Maiyalagan and published by CRC Press. This book was released on 2020-12-18 with total page 339 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium-ion batteries are the most promising among the secondary battery technologies, for providing high energy and high power required for hybrid electric vehicles (HEV) and electric vehicles (EV). Lithium-ion batteries consist of conventional graphite or lithium titanate as anode and lithium transition metal-oxides as cathode. A lithium salt dissolved in an aprotic solvent such as ethylene carbonate and diethylene carbonate is used as electrolyte. This rechargeable battery operates based on the principle of electrochemical lithium insertion/re-insertion or intercalation/de-intercalation during charging/discharging of the battery. It is essential that both electrodes have layered structure which should accept and release the lithium-ion. In advanced lithium-ion battery technologies, other than layered anodes are also considered. High cell voltage, high capacity as well as energy density, high Columbic efficiency, long cycle life, and convenient to fabricate any size or shape of the battery, are the vital features of this battery technology. Lithium-ion batteries are already being used widely in most of the consumer electronics such as mobile phones, laptops, PDAs etc. and are in early stages of application in HEV and EV, which will have far and wide implications and benefits to society. The book contains ten chapters, each focusing on a specific topic pertaining to the application of lithium-ion batteries in Electric Vehicles. Basic principles, electrode materials, electrolytes, high voltage cathodes, recycling spent Li-ion batteries and battery charge controller are addressed. This book is unique among the countable books focusing on the lithium-ion battery technologies for vehicular applications. It provides fundamentals and practical knowledge on the lithium-ion battery for vehicular application. Students, scholars, academicians, and battery and automobile industries will find this volume useful.