Correlation Analysis In Chemistry Of Solutions

Author : Roman Makitra
Publisher : CRC Press
ISBN 13 : 9047413245
Total Pages : 333 pages
Book Rating : 4.40/5 ( download)

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Download or read book Correlation Analysis in Chemistry of Solutions written by Roman Makitra and published by CRC Press. This book was released on 2004-07-01 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their a polaritya ) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate consta

Author : Roman Makitra
Publisher : CRC Press
ISBN 13 : 9067644064
Total Pages : 333 pages
Book Rating : 4.68/5 ( download)

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Download or read book Correlation Analysis in Chemistry of Solutions written by Roman Makitra and published by CRC Press. This book was released on 2004-07-01 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: The behavior of substances in solutions may not be adequately characterized by the effect of any single physicochemical parameter of solvents, nor are numerous semi-empirical scales of the solvent effect (their ‘polarity’) suitable for their limited selections only. In recent decades, it has been found that the variation of reaction rate constants in solutions or that spectral parameters of dissolved substances are determined by the total effect of different solvation processes. This monograph presents numerous examples of such an approach and characterizes various empirical and semi-empirical scales of solvent properties. It is shown that additional consideration of some structural parameters of solvents, namely, their cohesive energy and the molar volume, may provide for spreading this approach on homolytical and catalytic reaction. It is also shown that for the solvolysis reaction, one of the excessive reagents may represent either a reagent or a solvent, which requires additional consideration of its structural characteristics in the Hammeth equation. The application of the principle of free energy linearity also allowed adequate generalization of data on the effect of solvents on different physicochemical processes, such as dissolution of gases and solids in various solvents, swelling of polymers and solid fossil fuels, coal extraction, adsorption, absorption, diffusion, and chromatography. Special attention is paid to substance distribution between two immiscible phases. Properties of both an extractive phase and an active extractant dissolved in inert diluter are taken into account. The majority of these processes indicate the efficiency of solvent self-association factor that defines the energy consumption for formation of a void for an alien molecule injection.

Author : N. Chapman
Publisher : Springer Science & Business Media
ISBN 13 : 1461588316
Total Pages : 557 pages
Book Rating : 4.13/5 ( download)

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Download or read book Correlation Analysis in Chemistry written by N. Chapman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Correlation Analysis in Chemistry: Recent Advances, is a sequel to our Advances in Linear Free Energy Relationships. t The change in the title is designed to reflect more accurately the nature of the field and the contents of the volume. The term LFER is still widely used, but it is often applied rather loosely to correlation equations that are not LFER in the restricted sense of a relationship involving logarithms of rate or equili brium constants on each side of the equation. The term "correlation analysis" seems to us more appropriate for the whole subject. The use of this term has compelled us also to introduce "chemistry" into the title; we have preferred not to prefix this with "organic" on the grounds that several areas of interest are not "organic chemistry" as usually understood, al though, of course, traditional applications of the basic relationships asso ciated with the names of Hammett and of Taft continue to be of interest. In the first volume we sought through our authors to provide a series of general articles covering the various aspects of the field as they seemed to us. Since the book was the first international research monograph in its field, each chapter, while giving prominence to recent developments, did not neglect earlier work, so that each article presented a comprehensive account of its own area.

Author : N. Chapman
Publisher :
ISBN 13 : 9781461588320
Total Pages : 564 pages
Book Rating : 4.24/5 ( download)

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Download or read book Correlation Analysis in Chemistry written by N. Chapman and published by . This book was released on 1978-11-01 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : O. Exner
Publisher : Springer
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.51/5 ( download)

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Download or read book Correlation Analysis of Chemical Data written by O. Exner and published by Springer. This book was released on 1988-05-31 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : NB CHAPMAN (Ed)
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.99/5 ( download)

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Download or read book CORRELATION ANALYSIS IN CHEMISTRY - RECENT ADVANCES. written by NB CHAPMAN (Ed) and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : John Shorter
Publisher : Research Studies Press Limited
ISBN 13 :
Total Pages : 256 pages
Book Rating : 4.40/5 ( download)

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Download or read book Correlation Analysis of Organic Reactivity, with Particular Reference to Multiple Regression written by John Shorter and published by Research Studies Press Limited. This book was released on 1982 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : G. Marino
Publisher :
ISBN 13 :
Total Pages : 157 pages
Book Rating : 4.52/5 ( download)

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Download or read book Correlation Analysis in Organic Chemistry written by G. Marino and published by . This book was released on 1979* with total page 157 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author :
Publisher :
ISBN 13 :
Total Pages : 804 pages
Book Rating : 4.26/5 ( download)

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Download or read book Selected Water Resources Abstracts written by and published by . This book was released on 1991 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Author : John H. Montgomery
Publisher : CRC Press
ISBN 13 : 1420009133
Total Pages : 1746 pages
Book Rating : 4.32/5 ( download)

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Download or read book Groundwater Chemicals Desk Reference written by John H. Montgomery and published by CRC Press. This book was released on 2007-04-18 with total page 1746 pages. Available in PDF, EPUB and Kindle. Book excerpt: Building on the foundation set by its best-selling predecessors, the Groundwater Chemicals Desk Reference, Fourth Edition is both a broad, comprehensive desk reference and a guide for field research. This fourth edition contains more than 1,700 additional references, including adsorption data for more than 800 organic compounds and metals, s