Co2 Sequestration By Ex Situ Mineral Carbonation

Author : Aimaro Sanna
Publisher : World Scientific
ISBN 13 : 1786341611
Total Pages : 193 pages
Book Rating : 4.17/5 ( download)

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Download or read book Co2 Sequestration By Ex-situ Mineral Carbonation written by Aimaro Sanna and published by World Scientific. This book was released on 2016-12-22 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: To meet human energy needs, the use of fossil fuels is set to continue well into the second half of the 21st century. In order to avoid irreversible climate change, carbon dioxide capture and storage (CCS) must be integrated into industrial processes. Mineral carbonation (MC) is increasingly seen as an effective technology solution for CCS of CO2. With the potential to sequester billions of tonnes per year, remarkable developments in mineral carbonation technology are taking place, particularly in USA, Australia and the European Union.This book brings together some of the world's leading experts in the field of sequestration to provide a critical assessment of progress to date. Chapters cover the resources available for MC, and also give a critical analysis of the technologies developed for sequestering carbon from industrial and power plants, including the use of the resultant carbonated product. The studies conclude with evaluation of key technical and economic obstacles which need to be addressed for future research, development and application. CO2 Sequestration by Ex-Situ Mineral Carbonation is essential reading for engineers, chemists and materials scientists in graduate or research positions, and for those interested in sustainability, the environment and ecology.

Author : National Academies of Sciences, Engineering, and Medicine
Publisher : National Academies Press
ISBN 13 : 0309484529
Total Pages : 511 pages
Book Rating : 4.27/5 ( download)

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Download or read book Negative Emissions Technologies and Reliable Sequestration written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-04-08 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.

Author :
Publisher :
ISBN 13 :
Total Pages : 10 pages
Book Rating : 4.12/5 ( download)

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Download or read book Carbon Dioxide Sequestration by Ex-situ Mineral Carbonation written by and published by . This book was released on 2000 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: The process developed for carbon dioxide sequestration utilizes a slurry of water mixed with olivine- forsterite end member (Mg2SiO4), which is reacted with supercritical CO2 to produce magnesite (MgCO3). Carbon dioxide is dissolved in water to form carbonic acid, which likely dissociates to H and HCO3−. The H hydrolyzes the silicate mineral, freeing the cation (Mg{sup 2+}), which reacts with the HCO3− to form the solid carbonate. Results of the baseline tests, conducted on ground products of the natural mineral, have demonstrated that the kinetics of the reaction are slow at ambient temperature (22 degrees C) and subcritical CO2 pressures (below 7.4 MPa). However, at elevated temperature and pressure, coupled with continuous stirring of the slurry and gas dispersion within the water column, significant conversion to the carbonate occurs. Extent of reaction is roughly 90% within 24 h, at 185 degrees C and partial pressure of CO2 (P{sub CO{sub 2}}) of 11.6 MPa. Current studies suggest that reaction kinetics can be improved by pretreatment of the mineral, catalysis of the reaction, and/or solution modification. Subsequent tests are intended to examine these options, as well as other mineral groups.

Author : William K. O'Connor
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.34/5 ( download)

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Download or read book Ex-situ and In-situ Mineral Carbonation as a Means to Sequester Carbon Dioxide written by William K. O'Connor and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The U.S. Department of Energy's Albany Research Center is investigating mineral carbonation as a method of sequestering CO2 from coal-fired-power plants. Magnesium-silicate minerals such as serpentine [Mg3Si2O5(OH)4] and olivine (Mg2SiO4) react with CO2 to produce magnesite (MgCO3), and the calcium-silicate mineral, wollastonite (CaSiO3), reacts to form calcite (CaCO3). It is possible to carry out these reactions either ex situ (above ground in a traditional chemical processing plant) or in situ (storage underground and subsequent reaction with the host rock to trap CO2 as carbonate minerals). For ex situ mineral carbonation to be economically attractive, the reaction must proceed quickly to near completion. The reaction rate is accelerated by raising the activity of CO2 in solution, heat (but not too much), reducing the particle size, high-intensity grinding to disrupt the crystal structure, and, in the case of serpentine, heat-treatment to remove the chemically bound water. All of these carry energy/economic penalties. An economic study illustrates the impact of mineral availability and process parameters on the cost of ex situ carbon sequestration. In situ carbonation offers economic advantages over ex situ processes, because no chemical plant is required. Knowledge gained from the ex situ work was applied to long-term experiments designed to simulate in situ CO2 storage conditions. The Columbia River Basalt Group (CRBG), a multi-layered basaltic lava formation, has potentially favorable mineralogy (up to 25% combined concentration of Ca, Fe2+, and Mg cations) for storage of CO2. However, more information about the interaction of CO2 with aquifers and the host rock is needed. Core samples from the CRBG, as well as samples of olivine, serpentine, and sandstone, were reacted in an autoclave for up to 2000 hours at elevated temperatures and pressures. Changes in core porosity, secondary mineralizations, and both solution and solid chemistry were measured.

Author : V. Vishal
Publisher : Springer
ISBN 13 : 3319270192
Total Pages : 336 pages
Book Rating : 4.97/5 ( download)

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Download or read book Geologic Carbon Sequestration written by V. Vishal and published by Springer. This book was released on 2016-05-11 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This exclusive compilation written by eminent experts from more than ten countries, outlines the processes and methods for geologic sequestration in different sinks. It discusses and highlights the details of individual storage types, including recent advances in the science and technology of carbon storage. The topic is of immense interest to geoscientists, reservoir engineers, environmentalists and researchers from the scientific and industrial communities working on the methodologies for carbon dioxide storage. Increasing concentrations of anthropogenic carbon dioxide in the atmosphere are often held responsible for the rising temperature of the globe. Geologic sequestration prevents atmospheric release of the waste greenhouse gases by storing them underground for geologically significant periods of time. The book addresses the need for an understanding of carbon reservoir characteristics and behavior. Other book volumes on carbon capture, utilization and storage (CCUS) attempt to cover the entire process of CCUS, but the topic of geologic sequestration is not discussed in detail. This book focuses on the recent trends and up-to-date information on different storage rock types, ranging from deep saline aquifers to coal to basaltic formations.

Author : National Research Council
Publisher : National Academies Press
ISBN 13 : 0309305322
Total Pages : 235 pages
Book Rating : 4.27/5 ( download)

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Download or read book Climate Intervention written by National Research Council and published by National Academies Press. This book was released on 2015-06-17 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: The signals are everywhere that our planet is experiencing significant climate change. It is clear that we need to reduce the emissions of carbon dioxide and other greenhouse gases from our atmosphere if we want to avoid greatly increased risk of damage from climate change. Aggressively pursuing a program of emissions abatement or mitigation will show results over a timescale of many decades. How do we actively remove carbon dioxide from the atmosphere to make a bigger difference more quickly? As one of a two-book report, this volume of Climate Intervention discusses CDR, the carbon dioxide removal of greenhouse gas emissions from the atmosphere and sequestration of it in perpetuity. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration introduces possible CDR approaches and then discusses them in depth. Land management practices, such as low-till agriculture, reforestation and afforestation, ocean iron fertilization, and land-and-ocean-based accelerated weathering, could amplify the rates of processes that are already occurring as part of the natural carbon cycle. Other CDR approaches, such as bioenergy with carbon capture and sequestration, direct air capture and sequestration, and traditional carbon capture and sequestration, seek to capture CO2 from the atmosphere and dispose of it by pumping it underground at high pressure. This book looks at the pros and cons of these options and estimates possible rates of removal and total amounts that might be removed via these methods. With whatever portfolio of technologies the transition is achieved, eliminating the carbon dioxide emissions from the global energy and transportation systems will pose an enormous technical, economic, and social challenge that will likely take decades of concerted effort to achieve. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration will help to better understand the potential cost and performance of CDR strategies to inform debate and decision making as we work to stabilize and reduce atmospheric concentrations of carbon dioxide.

Author : National Academies of Sciences, Engineering, and Medicine
Publisher : National Academies Press
ISBN 13 : 0309483360
Total Pages : 257 pages
Book Rating : 4.60/5 ( download)

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Download or read book Gaseous Carbon Waste Streams Utilization written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-02-22 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the quest to mitigate the buildup of greenhouse gases in Earth's atmosphere, researchers and policymakers have increasingly turned their attention to techniques for capturing greenhouse gases such as carbon dioxide and methane, either from the locations where they are emitted or directly from the atmosphere. Once captured, these gases can be stored or put to use. While both carbon storage and carbon utilization have costs, utilization offers the opportunity to recover some of the cost and even generate economic value. While current carbon utilization projects operate at a relatively small scale, some estimates suggest the market for waste carbon-derived products could grow to hundreds of billions of dollars within a few decades, utilizing several thousand teragrams of waste carbon gases per year. Gaseous Carbon Waste Streams Utilization: Status and Research Needs assesses research and development needs relevant to understanding and improving the commercial viability of waste carbon utilization technologies and defines a research agenda to address key challenges. The report is intended to help inform decision making surrounding the development and deployment of waste carbon utilization technologies under a variety of circumstances, whether motivated by a goal to improve processes for making carbon-based products, to generate revenue, or to achieve environmental goals.

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.11/5 ( download)

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Download or read book Carbon Dioxide Sequestration by Direct Mineral Carbonation with Carbonic Acid written by and published by . This book was released on 2000 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Albany Research Center (ARC) of the U.S. Dept. of Energy (DOE) has been conducting a series of mineral carbonation tests at its Albany, Oregon, facility over the past 2 years as part of a Mineral Carbonation Study Program within the DOE. Other participants in this Program include the Los Alamos National Laboratory, Arizona State University, Science Applications International Corporation, and the DOE National Energy Technology Laboratory. The ARC tests have focused on ex-situ mineral carbonation in an aqueous system. The process developed at ARC utilizes a slurry of water mixed with a magnesium silicate mineral, olivine [forsterite end member (Mg2SiO4)], or serpentine [Mg3Si2O5(OH)4]. This slurry is reacted with supercritical carbon dioxide (CO2) to produce magnesite (MgCO3). The CO2 is dissolved in water to form carbonic acid (H2CO3), which dissociates to H+ and HCO3 -. The H+ reacts with the mineral, liberating Mg2+ cations which react with the bicarbonate to form the solid carbonate. The process is designed to simulate the natural serpentinization reaction of ultramafic minerals, and for this reason, these results may also be applicable to in-situ geological sequestration regimes. Results of the baseline tests, conducted on ground products of the natural minerals, have been encouraging. Tests conducted at ambient temperature (22 C) and subcritical CO2 pressures (below 73 atm) resulted in very slow conversion to the carbonate. However, when elevated temperatures and pressures are utilized, coupled with continuous stirring of the slurry and gas dispersion within the water column, significant reaction occurs within much shorter reaction times. Extent of reaction, as measured by the stoichiometric conversion of the silicate mineral (olivine) to the carbonate, is roughly 90% within 24 hours, using distilled water, and a reaction temperature of 185?C and a partial pressure of CO2 (PCO2) of 115 atm. Recent tests using a bicarbonate solution, under identical reaction conditions, have achieved roughly 83% conversion of heat treated serpentine and 84% conversion of olivine to the carbonate in 6 hours. The results from the current studies suggest that reaction kinetics can be improved by pretreatment of the mineral, catalysis of the reaction, or some combination of the two. Future tests are intended to examine a broader pressure/temperature regime, various pretreatment options, as well as other mineral groups.

Author : Luigi Marini
Publisher : Elsevier
ISBN 13 : 0080466885
Total Pages : 471 pages
Book Rating : 4.80/5 ( download)

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Download or read book Geological Sequestration of Carbon Dioxide written by Luigi Marini and published by Elsevier. This book was released on 2006-10-12 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer. * Provides applications for investigating and predicting geological carbon dioxide sequestration * Reviews the geochemical literature in the field * Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

Author : Susan Brantley
Publisher : Springer Science & Business Media
ISBN 13 : 0387735631
Total Pages : 843 pages
Book Rating : 4.34/5 ( download)

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Download or read book Kinetics of Water-Rock Interaction written by Susan Brantley and published by Springer Science & Business Media. This book was released on 2007-12-29 with total page 843 pages. Available in PDF, EPUB and Kindle. Book excerpt: Geochemical kinetics as a topic is now of importance to a wide range of geochemists in academia, industry, and government, and all geochemists need a rudimentary knowledge of the field. This book summarizes the fundamentals of geochemical kinetics with examples drawn especially from mineral dissolution and precipitation. It also encompasses discussion of high temperature processes and global geochemical cycle modeling. Analysis of textures of rocks, sediments, and mineral surfaces are incorporated throughout and provide a sub-theme of the book.