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Author : Arno Behr
Publisher :
ISBN 13 :
Total Pages : 180 pages
Book Rating : 4.17/5 ( download)
Download or read book Carbon Dioxide Activation by Metal Complexes written by Arno Behr and published by . This book was released on 1988 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Timothy J. Schmeier
Publisher :
ISBN 13 :
Total Pages : 260 pages
Book Rating : 4.87/5 ( download)
Download or read book Activation of Carbon Dioxide by Pincer Supported Transition Metal Complexes written by Timothy J. Schmeier and published by . This book was released on 2013 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : A.E. Shilov
Publisher : Springer Science & Business Media
ISBN 13 : 0306469456
Total Pages : 551 pages
Book Rating : 4.59/5 ( download)
Download or read book Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes written by A.E. Shilov and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 551 pages. Available in PDF, EPUB and Kindle. Book excerpt: hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Author : L. Vaska
Publisher :
ISBN 13 :
Total Pages : 17 pages
Book Rating : 4.78/5 ( download)
Download or read book Catalytic Activation of Carbon Dioxide by Metal Complexes written by L. Vaska and published by . This book was released on 1988 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: This paper summarizes some past and recent work from the author's laboratory on the reactions of carbon dioxide with metal complexes with the objective of suggesting the relevance of this research to some related biological systems. First, the various CO2-metal complex interactions in vivo and in vitro are briefly cited, followed by a description of the reversible activation of carbon dioxide by model rhodium and iridium compounds. Finally, recent results are presented on homogeneous catalytic hydrogenation/reduction of CO2 mediated by metal complexes, including a platinum cluster complex which catalyzes the carbon dioxide conversion at mild conditions. Keywords: Carbon dioxide, Metal complexes, Model compounds, Bicarbonato complexes, Homogeneous catalysis, Hydrogenation.
Author : Niklas Werner Kinzel
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.22/5 ( download)
Download or read book First-row Transition Metal Complexes for Electrochemical Carbon Dioxide Activation written by Niklas Werner Kinzel and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michele Aresta
Publisher : John Wiley & Sons
ISBN 13 : 9783527629923
Total Pages : 414 pages
Book Rating : 4.20/5 ( download)
Download or read book Carbon Dioxide as Chemical Feedstock written by Michele Aresta and published by John Wiley & Sons. This book was released on 2010-01-26 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the need for an up-to-date handbook, this ready reference closely investigates the use of CO2 for ureas, enzymes, carbamates, and isocyanates, as well as its use as a solvent, in electrochemistry, biomass utilization and much more. Edited by an internationally renowned and experienced researcher, this is a comprehensive source for every synthetic chemist in academia and industry.
Author : M.M. Taqui Khan
Publisher : Elsevier
ISBN 13 : 0323150381
Total Pages : 437 pages
Book Rating : 4.85/5 ( download)
Download or read book Activation Of Small Inorganic Molecules written by M.M. Taqui Khan and published by Elsevier. This book was released on 2012-12-02 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous Catalysis by Metal Complexes, Volume I: Activation of Small Inorganic Molecules reviews and systematizes the chemistry of the metal ion activation of the small diatomic molecules. The book discusses the activation of molecular hydrogen, molecular oxygen, molecular nitrogen, carbon monoxide, and nitric oxide.
Author : R. Bou-Moreno
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.41/5 ( download)
Download or read book The Design and Synthesis of Complexes for the Activation of Carbon Dioxide written by R. Bou-Moreno and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes developments in the studies of the activation and use of carbon dioxide as a building block in synthesis by early transition metal complexes. The proposed route required the reaction of carbon dioxide with a metal-imido complex via a heterocumulene metathesis to produce an isocyanate. An attempt at the use of molybdenum-imido complexes for the process generated a novel low valent molybdenum bisimido complex with no success in the activation of carbon dioxide. Generation of simple 12-electron titanium-imido complexes showed successful heterocumulene metathesis with isocyanates to develop a novel methodology for the synthesis of carbodiimides and ureas. The studies of this methodology proved a fourmembered ring metallocycle was an intermediate and suggested the mechanism of the process as plausible, as well as showing the activation of carbon dioxide. Our studies were concluded by the generation and modification of titanium-imido complexes to synthesise families of complexes containing aromatic imido ligands, which showed no reactivity with carbon dioxide with the exception of the 2,6- diisopropylphenylimido ligand. Unsuccessful isolation of alkylimido titanium complexes impeded the generation of families of complexes. In situ generation of alkylimido titanium complexes showed activation of carbon dioxide to generate ureas, proposing two consecutive heterocumulene metatheses first with carbon dioxide and a second with the generated isocyanate. Studies with intermediates and comparisons with the generation of carbodiimides support this mechanism.
Author : Arno Behr
Publisher :
ISBN 13 :
Total Pages : 180 pages
Book Rating : 4.09/5 ( download)
Download or read book Carbon Dioxide Activation by Metal Complexes written by Arno Behr and published by . This book was released on 1988 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Nianhong Liu
Publisher :
ISBN 13 :
Total Pages : 206 pages
Book Rating : 4.83/5 ( download)
Download or read book Activation of Carbon Dioxide and Dimerization of Terminal Acetylenes by Transition Metal Complexes written by Nianhong Liu and published by . This book was released on 1995 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt:
