Applied Homogeneous Catalysis

Author : Arno Behr
Publisher : John Wiley & Sons
ISBN 13 : 3527326413
Total Pages : 717 pages
Book Rating : 4.19/5 ( download)

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Download or read book Applied Homogeneous Catalysis written by Arno Behr and published by John Wiley & Sons. This book was released on 2012-04-16 with total page 717 pages. Available in PDF, EPUB and Kindle. Book excerpt: Auf fortgeschrittenem Niveau und mit didaktischem Anspruch bietet Ihnen dieser Band zahlreiche Fragen mit Antworten und eine breite Palette von Fallstudien aus der Industrie, ergänzt durch weiterführende Literaturhinweise und Referenzen der Originalliteratur. Insbesondere geht es um die modernsten katalytischen Prozesse mit ihren Anwendungen in der Pharmazie und der Feinchemikalien-Industrie, wobei auch kommerzielle Aspekte besprochen werden. Der Autor, ein erfahrener Dozent mit Industriepraxis, legt Chemikern und Chemieingenieuren damit ein praxistaugliches Hilfsmittel vor.

Author : Sumit Bhaduri
Publisher : John Wiley & Sons
ISBN 13 : 1118872479
Total Pages : 291 pages
Book Rating : 4.75/5 ( download)

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Download or read book Homogeneous Catalysis written by Sumit Bhaduri and published by John Wiley & Sons. This book was released on 2014-09-08 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts

Author : Boy Cornils
Publisher : John Wiley & Sons
ISBN 13 : 3527328971
Total Pages : 1778 pages
Book Rating : 4.70/5 ( download)

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Download or read book Applied Homogeneous Catalysis with Organometallic Compounds written by Boy Cornils and published by John Wiley & Sons. This book was released on 2017-12-26 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised third edition of this four-volume classic is fully updated and now includes such topics as as CH-activation and multicomponent reactions. It describes the most important reaction types, new methods and recent developments in catalysis. The internationally renowned editors and a plethora of international authors (including Nobel laureate R. Noyori) guarantee high quality content throughout the book. A "must read" for everyone in academia and industry working in this field.

Author : Can Li
Publisher : John Wiley & Sons
ISBN 13 : 3527675922
Total Pages : 860 pages
Book Rating : 4.20/5 ( download)

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Download or read book Bridging Heterogeneous and Homogeneous Catalysis written by Can Li and published by John Wiley & Sons. This book was released on 2014-04-03 with total page 860 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.

Author : A. Mortreux
Publisher : Springer Science & Business Media
ISBN 13 : 9400938977
Total Pages : 371 pages
Book Rating : 4.77/5 ( download)

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Download or read book Industrial Applications of Homogeneous Catalysis written by A. Mortreux and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.

Author : Gheorghe Duca
Publisher : Springer Science & Business Media
ISBN 13 : 364224629X
Total Pages : 484 pages
Book Rating : 4.96/5 ( download)

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Download or read book Homogeneous Catalysis with Metal Complexes written by Gheorghe Duca and published by Springer Science & Business Media. This book was released on 2012-06-15 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.

Author : Piet W.N.M. van Leeuwen
Publisher : Springer Science & Business Media
ISBN 13 : 9401104751
Total Pages : 219 pages
Book Rating : 4.53/5 ( download)

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Download or read book Theoretical Aspects of Homogeneous Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication is the first to present the quantitative application of quantum chemistry to organometallic reactions. Great progress has been made in recent years in the calculation of transition states of organometallic conversions in both homo and heterogeneous catalysis. This volume, which contains seven contributions by leading scientists, deals with key reactions of homogeneous catalysis including oxidative addition, migratory insertions, 2+2 additions, the Wacker reaction, and epoxidation. The book provides experimental chemists with an up-to-date overview of the state of the art in this field, and will stimulate an adjustment of views previously based on semiempirical calculations. For researchers and advanced graduate students whose work involves organometallics and catalysis.

Author : George W. Parshall
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 368 pages
Book Rating : 4.97/5 ( download)

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Download or read book Homogeneous Catalysis written by George W. Parshall and published by Wiley-Interscience. This book was released on 1992-08-07 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: The broadening technical advances in the production of pharmaceuticals, flavors, and fragrances have more than doubled the industrial applications of soluble transition metal catalysts. Indeed, transition metal catalysts have become an ascendant feature of a heightened academic interest in organometallic chemistry. This Second Edition of the landmark text offers a clear, systematic look at the state-of-the-science of homogeneous catalytic reactions. Focusing on specific processes, rather than principles of coordination or organometallic chemistry, this updated edition is an A-to-Z compilation of the homogeneous catalytic reactions commonly used in industry or that have broad application in the organic synthesis laboratory. Documenting examples of homogeneous catalytic reactions used in current commercial processes, this newest edition features Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol processes for dimerizing propylene as well as Du Pont's hydrocyanation process. Detailed coverage also includes isomerization of simple olefins, mechanism of olefin hydrogenation, oligomerization of olefins, chain transfer catalysis, reactions of carbon monoxide, specialty chemicals, reactions of acetylenes, esterification, polycondensation, and related processes. Featuring the latest findings in its existing coverage on pharmaceuticals, agricultural chemicals, flavors, fragrances, and electronic chemicals, this Second Edition clearly details the science's growing influence and practicality in industry and the lab. Organic and inorganic chemists, instructors, and students will find Homogeneous Catalysis, Second Edition a clear, up-to-date compendium of the catalytic reactionssharpening chemistry's cutting edge.

Author : Robin Whyman
Publisher : OUP Oxford
ISBN 13 : 9780198559177
Total Pages : 97 pages
Book Rating : 4.78/5 ( download)

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Download or read book Applied Organometallic Chemistry and Catalysis written by Robin Whyman and published by OUP Oxford. This book was released on 2001-07-05 with total page 97 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Primer has two main objectives: to provide an overview of the influence of organometallic chemistry on homogeneous and heterogenous catalysis and to provide an account of the principle commercial applications of homogeneous catalysis in industry. The book builds on the coverage of organometallic chemistry in two Primers by Bochmann, OCPs 12 and 13.

Author : J.A. Moulijn
Publisher : Elsevier
ISBN 13 : 9780080886985
Total Pages : 462 pages
Book Rating : 4.81/5 ( download)

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Download or read book Catalysis written by J.A. Moulijn and published by Elsevier. This book was released on 1993-09-09 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis is a multidisciplinary activity which is reflected in this book. The editors have chosen a novel combination of basic disciplines - homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis with metallic and non-metallic solids. The main theme of the book is the molecular approach to industrial catalysis. In the introductory section Chapter 1 presents a brief survey of the history of industrial heterogeneous and homogeneous catalysis. Subsequently, a selection of current industrial catalytic processes is described (Chapter 2). A broad spectrum of important catalytic applications is presented, including the basic chemistry, some engineering aspects, feedstock sources and product utilisation. In Chapter 3, kinetic principles are treated. The section on fundamental catalysis begins with a description of the bonding in complexes and to surfaces (Chapter 4). The elementary steps on complexes and surfaces are described. The chapter on heterogeneous catalysis (5) deals with the mechanistic aspects of three groups of important reactions: syn-gas conversion, hydrogenation, and oxidation. The main principles of metal and metal oxide catalysis are presented. Likewise, the chapter on homogeneous catalysis (6) concentrates on three reactions representing examples from three areas: carbonylation, polymerization, and asymmetric catalysis. Identification by in situ techniques has been included. Many constraints to the industrial use of a catalyst have a macroscopic origin. In applied catalysis it is shown how catalytic reaction engineering deals with such macroscopic considerations in heterogeneous as well as homogeneous catalysis (Chapter 7). The transport and kinetic phenomena in both model reactors and industrial reactors are outlined. The section on catalyst preparation (Chapters 8 and 9) is concerned with the preparation of catalyst supports, zeolites, and supported catalysts, with an emphasis on general principles and mechanistic aspects. For the supported catalysts the relation between the preparative method and the surface chemistry of the support is highlighted. The molecular approach is maintained throughout. The first chapter (10) in the section on catalyst characterization summarizes the most common spectroscopic techniques used for the characterisation of heterogeneous catalysts such as XPS, Auger, EXAFS, etc. Temperature programmed techniques, which have found widespread application in heterogeneous catalysis both in catalyst characterization and simulation of pretreatment procedures, are discussed in Chapter 11. A discussion of texture measurement, theory and application, concludes this section (12). The final chapter (13) gives an outline of current trends in catalysis. Two points of view are adopted: the first one focusses on developments in process engineering. Most often these have their origin in demands by society for better processes. The second point of view draws attention to the autonomous developments in catalysis, which is becoming one of the frontier sciences of physics and chemistry. In this book emphasis is on those reactions catalyzed by heterogeneous and homogeneous catalysts of industrial relevance. The integrative treatment of the subject matter involves many disciplines, consequently, the writing of the book has been a multi-author task. The editors have carefully planned and harmonized the contents of the chapters.